Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/8253
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dc.contributor.authorSerra, M. Elisa Silva-
dc.contributor.authorMurtinho, Dina-
dc.contributor.authorGonsalves, A. M. d'A. Rocha-
dc.date.accessioned2009-02-09T14:30:52Z-
dc.date.available2009-02-09T14:30:52Z-
dc.date.issued2008en_US
dc.identifier.citationApplied Organometallic Chemistry. 22:9 (2008) 488-493en_US
dc.identifier.urihttp://hdl.handle.net/10316/8253-
dc.description.abstractA series of chiral delta-diamines and structurally analogous delta-amino alcohols derived from natural tartaric acid were synthesized and a comparative study of their activity and selectivity in the enantioselective alkylation of aromatic aldehydes was carried out. Our results show that in general the delta-diamines were found to be better chiral inducers than the corresponding delta-amino alcohols. The highest selectivity was observed when benzaldehyde was alkylated in the presence of the benzylic diamine, giving (R)-1-phenylpropanol with an ee of 42%. Copyright © 2008 John Wiley & Sons, Ltd.en_US
dc.language.isoengeng
dc.rightsopenAccesseng
dc.titleA comparative study of reactivity and selectivity of chiral diamines and structurally analogous amino alcohol ligands in enantioselective alkylations with diethylzincen_US
dc.typearticleen_US
dc.identifier.doi10.1002/aoc.1428en_US
item.languageiso639-1en-
item.grantfulltextopen-
item.fulltextCom Texto completo-
crisitem.author.deptFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.deptFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.deptFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.parentdeptUniversidade de Coimbra-
crisitem.author.parentdeptUniversidade de Coimbra-
crisitem.author.parentdeptUniversidade de Coimbra-
crisitem.author.researchunitCoimbra Chemistry Center-
crisitem.author.researchunitCoimbra Chemistry Center-
crisitem.author.researchunitCoimbra Chemistry Center-
crisitem.author.parentresearchunitFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.parentresearchunitFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.parentresearchunitFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.orcid0000-0002-4562-7072-
crisitem.author.orcid0000-0002-1391-9855-
crisitem.author.orcid0000-0001-9987-7301-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
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