Processing laser ablated plasmonic nanoparticle aerosols with nonthermal dielectric barrier discharge jets of argon and helium and plasma induced effects

Abstract

Dielectric-barrier-discharge (DBD) plasma jets provide viable state-of-the-art nonthermal processes for a wide range of nanomaterials including particle transport and deposition. We report the interaction of argon and helium plasma jets with the particle aerosol, produced by ns laser ablation of a silver target and subsequently their transport for deposition on a distant substrate. The nanofeatures and functionality of the nanoparticles, entrained and deposited with the two plasma jets were compared using high-resolution electron microscopy, helium ion microscopy, scanning electron microscopy, ultraviolet-visible spectroscopy, and in terms of the SERS effect. The plasma jet facilitates the transport of the particle aerosol under the upshot of plasma ionic wind, caused by the high electric field in the plasma. Compared to the helium plasma jet, the argon plasma jet leads to a relatively large particle deposition and promotes the formation of aggregates. The helium plasma jet enabled the deposition of spatially well dispersed particles. In both cases, the deposited particle was crystalline and plasmonic active. The plasma-driven altered morphology, expedient particle transport, and formation of agglomerates or spatially well dispersed particles are explained in plasma-induced ionic-wind, and dusty plasma framework. The findings are novel and interesting from the perspective of plasma-surface deposition, surface nanoengineering, and nanomaterial processing for applications in sensing, catalysis, surgical tools, futuristic coating technology, and heat-sensible biological activities.