Please use this identifier to cite or link to this item: https://hdl.handle.net/10316/105415
DC FieldValueLanguage
dc.contributor.authorDe Bon, Francesco-
dc.contributor.authorCarlan, Gian Marco-
dc.contributor.authorTognella, Enrico-
dc.contributor.authorIsse, Abdirisak Ahmed-
dc.date.accessioned2023-02-27T10:41:43Z-
dc.date.available2023-02-27T10:41:43Z-
dc.date.issued2021-
dc.identifier.issn2227-9717pt
dc.identifier.urihttps://hdl.handle.net/10316/105415-
dc.description.abstractElectrochemically mediated atom transfer radical polymerization (eATRP) of styrene was studied in detail by using CuBr2/TPMA (TPMA = tris(2-pyridylmethyl)amine) as a catalyst. Redox properties of various Cu(II) species were investigated in CH3CN, dimethylformamide (DMF), and dimethyl sulfoxide (DMSO) both in the absence and presence of 50% (v/v) styrene. This investigation together with preliminary eATRP experiments at 80 C indicated DMF as the best solvent. The effects of catalyst, monomer, and initiator concentrations were also examined. The livingness of the polymerization was studied by chain extension and electrochemical temporal control of polymerization.pt
dc.language.isoengpt
dc.publisherMDPIpt
dc.rightsopenAccesspt
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt
dc.subjectstyrenept
dc.subjecteATRPpt
dc.subjecttemporal controlpt
dc.subjectcopper catalystpt
dc.titleExploring Electrochemically Mediated ATRP of Styrenept
dc.typearticle-
degois.publication.firstPage1327pt
degois.publication.issue8pt
degois.publication.titleProcessespt
dc.peerreviewedyespt
dc.identifier.doi10.3390/pr9081327pt
degois.publication.volume9pt
dc.date.embargo2021-01-01*
uc.date.periodoEmbargo0pt
item.fulltextCom Texto completo-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypearticle-
item.grantfulltextopen-
item.cerifentitytypePublications-
crisitem.author.researchunitCEMMPRE - Centre for Mechanical Engineering, Materials and Processes-
crisitem.author.orcid0000-0003-1858-3390-
Appears in Collections:I&D CEMMPRE - Artigos em Revistas Internacionais
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