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https://hdl.handle.net/10316/10440
Title: | Measurements and Correlation of High-Pressure Densities of Imidazolium-Based Ionic Liquids | Authors: | Tomé, Luciana I. N. Carvalho, Pedro J. Freire, Mara G. Marrucho, Isabel M. Fonseca, Isabel M. A. Ferreira, Abel G. M. Coutinho, João A. P. Gardas, Ramesh L. |
Issue Date: | 14-Aug-2008 | Publisher: | American Chemical Society | Citation: | Journal of Chemical & Engineering Data. 53:8 (2008) 1914-1921 | Abstract: | In the present work, experimental density measurements are reported along with the derived thermodynamic properties, such as the isothermal compressibility (κT), the isobaric expansivity (αp), and the thermal pressure coefficient (γv) for imidazolium-based ionic liquids (ILs), namely, 1-ethyl-3-methylimidazolium methylsulfate [C2mim][MeSO4], 1-ethyl-3-methylimidazolium ethylsulfate [C2mim][EtSO4], 1,3-diethylimidazolium bis(trifluoromethylsulfonyl)imide [C2eim][Tf2N], and 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [C10mim][Tf2N] in the pressure (0.10 < P/MPa < 35.00) and temperature (293.15 < T/K < 393.15) domains. It is shown that experimental densities are in good agreement with the predicted densities obtained by the Gardas and Coutinho method and the correlation using the Tait equation and Sanchez−Lacombe equation of state. | URI: | https://hdl.handle.net/10316/10440 | ISSN: | 0021-9568 | DOI: | 10.1021/je800316b | Rights: | openAccess |
Appears in Collections: | FCTUC Eng.Química - Artigos em Revistas Internacionais |
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Measurements and Correlation of High-Pressure Densities.pdf | 168.65 kB | Adobe PDF | View/Open |
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