Please use this identifier to cite or link to this item: https://hdl.handle.net/10316/91154
DC FieldValueLanguage
dc.contributor.authorLamsaf, H.-
dc.contributor.authorElghadraoui, E. H.-
dc.contributor.authorLourenço, Rui Fausto-
dc.contributor.authorOulmekki, A.-
dc.contributor.authorCosta, B. F. O.-
dc.date.accessioned2020-10-10T12:01:43Z-
dc.date.available2020-10-10T12:01:43Z-
dc.date.issued2019-09-13-
dc.identifier.issn1557-1939pt
dc.identifier.issn1557-1947pt
dc.identifier.urihttps://hdl.handle.net/10316/91154-
dc.description.abstractA new mixed-valence diphosphate, Zn2+5Fe3+2(P2O7)4, was synthesized from FeII5FeIII2(P2O7)4 via the “solid way” route, by substitution of FeII by ZnII. The obtained X-ray data confirmed the crystallization of the compound in the C2221 symmetry space group (orthorhombic). Magnetic measurements were performed showing that, at room temperature, the compound is paramagnetic and that the Néel temperature is 15.44(20) K. The compound was also investigated by infrared and Raman spectroscopies, in particular to characterize the (P2O7)4− and M–O vibrations.pt
dc.language.isoengpt
dc.publisherSpringer Naturept
dc.relationinfo:eu-repo/grantAgreement/FCT/04564/2016/PTpt
dc.relationinfo:eu-repo/grantAgreement/QREN-Mais Centro/ICT-2009-02-012-1890/PTpt
dc.relationinfo:eu-repo/grantAgreement/FCT/UI0313/QUI/2013/PTpt
dc.relationinfo:eu-repo/grantAgreement/MATIS/CENTRO-01-0145-FEDER-000014/PTpt
dc.rightsembargoedAccesspt
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt
dc.subjectNew mixed-valence diphosphatept
dc.subjectX-ray diffractionpt
dc.subjectRaman and infrared spectroscopiespt
dc.subjectMagnetometrypt
dc.titleSynthesis, Structural Studies, and Magnetic Properties of a New Mixed-Valence Diphosphate: Zn2+5Fe3+2(P2O7)4pt
dc.typearticle-
degois.publication.firstPage1007pt
degois.publication.lastPage1012pt
degois.publication.issue9pt
degois.publication.titleJournal of Superconductivity and Novel Magnetismpt
dc.relation.publisherversionhttps://link.springer.com/article/10.1007/s10948-019-05263-wpt
dc.peerreviewedyespt
dc.identifier.doi10.1007/s10948-019-05263-wpt
degois.publication.volume33pt
dc.date.embargo2020-09-12*
uc.date.periodoEmbargo365pt
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypearticle-
item.cerifentitytypePublications-
item.grantfulltextopen-
item.fulltextCom Texto completo-
item.languageiso639-1en-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.orcid0000-0002-8264-6854-
Appears in Collections:I&D CQC - Artigos em Revistas Internacionais
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