Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/90922
Title: Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes
Authors: Lopes, Susana M. M. 
Melo, Teresa M. V. D. Pinho e 
Issue Date: 6-Mar-2020
Publisher: ACS Publications
Project: UIDB/00313/2020 
Serial title, monograph or event: The Journal of organic chemistry
Volume: 85
Abstract: The synthesis of bilanes and hexapyrroles containing an oxime functionality, prepared by two and three consecutive hetero-Diels-Alder reactions (or conjugated additions) between nitrosoalkenes and dipyrromethanes, is described. Bilanes underwent oxidative macrocyclization to afford a new class of trans-A2B-corroles. Porphyrins could also be obtained by reacting bilanes with aldehydes in the presence of trifluoroacetic acid, followed by an oxidative step.
URI: http://hdl.handle.net/10316/90922
ISSN: 0022-3263
1520-6904
DOI: 10.1021/acs.joc.9b03151
Rights: embargoedAccess
Appears in Collections:I&D CQC - Artigos em Revistas Internacionais

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