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https://hdl.handle.net/10316/90922
Title: | Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes | Authors: | Lopes, Susana M. M. Melo, Teresa M. V. D. Pinho e |
Issue Date: | 6-Mar-2020 | Publisher: | ACS Publications | Project: | UIDB/00313/2020 | Serial title, monograph or event: | The Journal of organic chemistry | Volume: | 85 | Abstract: | The synthesis of bilanes and hexapyrroles containing an oxime functionality, prepared by two and three consecutive hetero-Diels-Alder reactions (or conjugated additions) between nitrosoalkenes and dipyrromethanes, is described. Bilanes underwent oxidative macrocyclization to afford a new class of trans-A2B-corroles. Porphyrins could also be obtained by reacting bilanes with aldehydes in the presence of trifluoroacetic acid, followed by an oxidative step. | URI: | https://hdl.handle.net/10316/90922 | ISSN: | 0022-3263 1520-6904 |
DOI: | 10.1021/acs.joc.9b03151 | Rights: | embargoedAccess |
Appears in Collections: | I&D CQC - Artigos em Revistas Internacionais |
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Lopes2020JOrgChem.pdf | 1.09 MB | Adobe PDF | View/Open |
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