Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/8237
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Serpa, Carlos | - |
dc.contributor.author | Gomes, Paulo J. S. | - |
dc.contributor.author | Arnaut, Luis G. | - |
dc.contributor.author | Melo, J. Seixas de | - |
dc.contributor.author | Formosinho, Sebastião J. | - |
dc.date.accessioned | 2009-02-09T14:30:41Z | - |
dc.date.available | 2009-02-09T14:30:41Z | - |
dc.date.issued | 2006 | en_US |
dc.identifier.citation | ChemPhysChem. 7:12 (2006) 2533-2539 | en_US |
dc.identifier.uri | https://hdl.handle.net/10316/8237 | - |
dc.description.abstract | We measured the temperature dependence (from +32 to -50 °C) of charge-recombination rates between contact radical ion pairs in isopropyl ether. In the systems selected for this study, aromatic hydrocarbon cations are the electron acceptors and the fumaronitrile anion is the electron donor. Nearly quantitative electron transfers occur at all temperatures. The charge recombinations have excess exothermicities of -60 kcal mol-1 and exhibit a very weak temperature dependence. Our observations emphasize the absence of solvent effects and the relevance of nuclear tunneling in charge recombinations. | en_US |
dc.language.iso | eng | eng |
dc.rights | openAccess | eng |
dc.title | Temperature Dependence of Ultra-Exothermic Charge Recombinations13 | en_US |
dc.type | article | en_US |
dc.identifier.doi | 10.1002/cphc.200600467 | en_US |
uc.controloAutoridade | Sim | - |
item.fulltext | Com Texto completo | - |
item.grantfulltext | open | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
item.openairetype | article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.dept | Faculty of Sciences and Technology | - |
crisitem.author.dept | Faculty of Sciences and Technology | - |
crisitem.author.parentdept | University of Coimbra | - |
crisitem.author.parentdept | University of Coimbra | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CISUC - Centre for Informatics and Systems of the University of Coimbra | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0001-7004-0110 | - |
crisitem.author.orcid | 0000-0002-4122-9018 | - |
crisitem.author.orcid | 0000-0002-3223-4819 | - |
crisitem.author.orcid | 0000-0001-9708-5079 | - |
crisitem.author.orcid | 0000-0001-6607-0026 | - |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
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