Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/80891
DC Field | Value | Language |
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dc.contributor.author | Martins, João P | - |
dc.date.accessioned | 2018-09-24T15:32:38Z | - |
dc.date.available | 2018-09-24T15:32:38Z | - |
dc.date.issued | 2013 | - |
dc.identifier.uri | https://hdl.handle.net/10316/80891 | - |
dc.description.abstract | In the title compound, [K(C10H5ClO2F3)(H2O)] n , the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chloro-phenyl-4,4,4-tri-fluoro-butane-1,3-dionate anions and by two O atoms of water mol-ecules. The μ4-bridging character of the anion and the μ2-bridging of the water mol-ecule lead to the formation of layers parallel to (100). The coordinating water mol-ecules are also involved in O-H⋯O hydrogen bonds that reinforce the mol-ecular cohesion within the layers, which are stacked along [100]. The β-diketonate anion is not planar, with an angle of 31.78 (10)° between the mean planes of the diketonate group and the chloro-phenyl ring. | pt |
dc.language.iso | por | pt |
dc.rights | openAccess | pt |
dc.title | Poly[μ2-aqua-μ4-[1-(4-chloro-phen-yl)-4,4,4-tri-fluoro-butane-1,3-dionato]-potassium] | pt |
dc.type | article | - |
degois.publication.firstPage | m422-3 | pt |
degois.publication.lastPage | m423 | pt |
degois.publication.issue | Pt 7 | pt |
dc.peerreviewed | yes | pt |
dc.identifier.doi | 10.1107/S1600536813017388 | pt |
degois.publication.volume | 69 | pt |
dc.date.embargo | 2013-01-01 | * |
dc.date.periodoembargo | 0 | pt |
dc.identifier.pmid | 24046587 | - |
item.grantfulltext | open | - |
item.fulltext | Com Texto completo | - |
item.openairetype | article | - |
item.languageiso639-1 | pt | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
Files in This Item:
File | Description | Size | Format | |
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wm2752.pdf | 778.85 kB | Adobe PDF | View/Open |
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