Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/80891
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Martins, João P | - |
dc.date.accessioned | 2018-09-24T15:32:38Z | - |
dc.date.available | 2018-09-24T15:32:38Z | - |
dc.date.issued | 2013 | - |
dc.identifier.uri | https://hdl.handle.net/10316/80891 | - |
dc.description.abstract | In the title compound, [K(C10H5ClO2F3)(H2O)] n , the two independent K(+) ions are located on a twofold rotation axis. For each of the cations, the distorted cubic coordination environment is defined by two F and four O atoms of symmetry-related 1,4-chloro-phenyl-4,4,4-tri-fluoro-butane-1,3-dionate anions and by two O atoms of water mol-ecules. The μ4-bridging character of the anion and the μ2-bridging of the water mol-ecule lead to the formation of layers parallel to (100). The coordinating water mol-ecules are also involved in O-H⋯O hydrogen bonds that reinforce the mol-ecular cohesion within the layers, which are stacked along [100]. The β-diketonate anion is not planar, with an angle of 31.78 (10)° between the mean planes of the diketonate group and the chloro-phenyl ring. | pt |
dc.language.iso | por | pt |
dc.rights | openAccess | pt |
dc.title | Poly[μ2-aqua-μ4-[1-(4-chloro-phen-yl)-4,4,4-tri-fluoro-butane-1,3-dionato]-potassium] | pt |
dc.type | article | - |
degois.publication.firstPage | m422-3 | pt |
degois.publication.lastPage | m423 | pt |
degois.publication.issue | Pt 7 | pt |
dc.peerreviewed | yes | pt |
dc.identifier.doi | 10.1107/S1600536813017388 | pt |
degois.publication.volume | 69 | pt |
dc.date.embargo | 2013-01-01 | * |
dc.date.periodoembargo | 0 | pt |
dc.identifier.pmid | 24046587 | - |
item.fulltext | Com Texto completo | - |
item.grantfulltext | open | - |
item.languageiso639-1 | pt | - |
item.cerifentitytype | Publications | - |
item.openairetype | article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
wm2752.pdf | 778.85 kB | Adobe PDF | View/Open |
SCOPUSTM
Citations
2
checked on Oct 7, 2024
WEB OF SCIENCETM
Citations
10
2
checked on Oct 2, 2024
Page view(s)
277
checked on Oct 8, 2024
Download(s)
168
checked on Oct 8, 2024
Google ScholarTM
Check
Altmetric
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.