Title: Allylic and benzylic oxidation reactions with sodium chlorite
Authors: Silvestre, Samuel M. 
Salvador, Jorge A. R. 
Keywords: Sodium chlorite;Allylic oxidation;Benzylic oxidation;Transition-metal free
Issue Date: 2007
Citation: Tetrahedron. 63:11 (2007) 2439-2445
Abstract: Various allylic and benzylic substrates were selectively oxidized to the corresponding enones in good yields using sodium chlorite, either in combination with tert-butyl hydroperoxide in stoichiometric conditions, or associated with N-hydroxyphthalimide as catalyst. These oxidation reactions were effectively and economically performed under mild, transition-metal free conditions and therefore the dual challenge of cost effectiveness and benign nature of the processes was met with.
URI: http://hdl.handle.net/10316/5861
Rights: openAccess
Appears in Collections:FFUC- Artigos em Revistas Internacionais

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