Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/5213
Title: | Room temperature and low-temperature absorption and emission spectra of some polypyridylruthenium(II) 3.2.1 complexes | Authors: | Silva, M. I. Burrows, H. D. Formosinho, S. J. Miguel, M. da G. |
Keywords: | Polypyridine ruthenium(II) complexes; Luminescence; Triplet energy acceptors; Organic light emitting devices | Issue Date: | 2001 | Citation: | Journal of Molecular Structure. 565-566:(2001) 79-82 | Abstract: | Electronic absorption and luminescence spectra are reported for a series of complexes of type [Ru(tpy)(L-L)(py)]2+, where tpy and py are 2,2',2''-terpyridine and pyridine, and L-L represents the bidentate ligands bipyridyl, 4,4'-dimethylbipyridyl, 4-nitrobipyridyl, oxalate and acetylacetonate. The effect of solvent polarity and temperature on their spectral and light emission properties is studied. Energies are reported for the lowest-energy 3MLCT* excited state, and on the basis of these it is suggested that the complexes may make good triplet energy acceptors for use in organic and polymeric light emitting devices. | URI: | https://hdl.handle.net/10316/5213 | DOI: | 10.1016/S0022-2860(00)00779-1 | Rights: | openAccess |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
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filed8318c700fa14bda976ee78aa7a54fc4.pdf | 96.22 kB | Adobe PDF | View/Open |
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