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Title: | Tetraphenylethylene. Infrared and nuclear magnetic resonance evidence on the nature of the dianion | Authors: | Eargle Jr., Dolan H. | Issue Date: | 1971 | Publisher: | American Chemical Society | Citation: | Journal of the American Chemical Society. 93:16 (1971) 3859–3862 | Abstract: | The ir aryl skeletal vibrations (1600-cm-' region) and the nmr spectrum of tetraphenylethylene dianion (TPE2-) have been recorded. Evidence points to the conclusion that the antibonding electrons of the dianion are highly delocalized and that the K-bonding electrons of TPE2- essentially retain their bonding power, requiring the dianion t o assume a nearly planar configuration | URI: | https://hdl.handle.net/10316/12878 | ISSN: | 0002-7863 | DOI: | 10.1021/ja00745a004 | Rights: | openAccess |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
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Tetraphenylethylene. Infrared and nuclear magnetic resonance.pdf | 514.05 kB | Adobe PDF | View/Open |
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