Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/114025
DC Field | Value | Language |
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dc.contributor.author | de Souza, Vitória Barbosa | - |
dc.contributor.author | da Rocha, Vinícius N | - |
dc.contributor.author | Piquini, Paulo Cesar | - |
dc.contributor.author | Chaves, Otávio Augusto | - |
dc.contributor.author | Iglesias, Bernardo A | - |
dc.date.accessioned | 2024-03-15T10:38:49Z | - |
dc.date.available | 2024-03-15T10:38:49Z | - |
dc.date.issued | 2023-02-01 | - |
dc.identifier.issn | 1420-3049 | pt |
dc.identifier.uri | https://hdl.handle.net/10316/114025 | - |
dc.description.abstract | The trans-A2B-corrole series was prepared starting with 5-(pentafluorophenyl)dipyrromethene, which was then reacted with respective aryl-substituted aldehyde by Gryko synthesis. It was further characterized by HRMS and electrochemical methods. In addition, we investigated experimental photophysical properties (absorption, emission by steady-state and time-resolved fluorescence) in several solvents and TDDFT calculations, aggregation, photostability and reactive oxygen species generation (ROS), which are relevant when selecting photosensitizers used in photodynamic therapy and many other photo-applications. In addition, we also evaluated the biomolecule-binding properties with CT-DNA and HSA by spectroscopy, viscometry and molecular docking calculations assays. | pt |
dc.description.sponsorship | CNPq (Universal—403210/2021-6 and PQ—305458/2021-3), CAPES (Finance code 001) and FAPERGS grants (PQ Gaucho—21/2551-0002114-4). P.C. Piquini also to thanks CNPq (312388/2018-7), CAPES and FAPERGS. | pt |
dc.language.iso | eng | pt |
dc.publisher | MDPI | pt |
dc.relation | UIDB/00313/2020 | pt |
dc.rights | openAccess | pt |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt |
dc.subject | corroles | pt |
dc.subject | trans-A2B-corroles | pt |
dc.subject | photophysics | pt |
dc.subject | photobiology | pt |
dc.subject.mesh | Molecular Docking Simulation | pt |
dc.subject.mesh | Photobiology | pt |
dc.subject.mesh | Porphyrins | pt |
dc.subject.mesh | Photochemotherapy | pt |
dc.title | Effects of Substituents on the Photophysical/Photobiological Properties of Mono-Substituted Corroles | pt |
dc.type | article | - |
degois.publication.firstPage | 1385 | pt |
degois.publication.issue | 3 | pt |
degois.publication.title | Molecules | pt |
dc.peerreviewed | yes | pt |
dc.identifier.doi | 10.3390/molecules28031385 | pt |
degois.publication.volume | 28 | pt |
dc.date.embargo | 2023-02-01 | * |
uc.date.periodoEmbargo | 0 | pt |
item.fulltext | Com Texto completo | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | open | - |
item.languageiso639-1 | en | - |
item.openairetype | article | - |
item.cerifentitytype | Publications | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0001-6211-7659 | - |
crisitem.project.grantno | Coimbra Chemistry Center | - |
Appears in Collections: | I&D CQC - Artigos em Revistas Internacionais FCTUC Química - Artigos em Revistas Internacionais |
Files in This Item:
File | Description | Size | Format | |
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Effects-of-Substituents-on-the-PhotophysicalPhotobiological-Properties-of-MonoSubstituted-CorrolesMolecules.pdf | 7.93 MB | Adobe PDF | View/Open |
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