Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/107530
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Tomé, Vanessa Almeida | - |
dc.contributor.author | Calvete, Mário J. F. | - |
dc.contributor.author | Vinagreiro, Carolina S. | - |
dc.contributor.author | Aroso, Rafael T. | - |
dc.contributor.author | Pereira, Mariette M. | - |
dc.date.accessioned | 2023-07-19T08:16:31Z | - |
dc.date.available | 2023-07-19T08:16:31Z | - |
dc.date.issued | 2018 | - |
dc.identifier.issn | 2073-4344 | pt |
dc.identifier.uri | https://hdl.handle.net/10316/107530 | - |
dc.description.abstract | The amide peptide bond type linkage is one of the most natural conjugations available, present in many biological synthons and pharmaceutical drugs. Hence, aiming the direct conjugation of potentially biologically active compounds to phthalocyanines, herein we disclose a new strategy for direct modulation of phthalonitriles, inspired by an attractive synthetic strategy for the preparation of carboxamides based on palladium-catalyzed aminocarbonylation of aryl halides in the presence of carbon monoxide (CO) which, to our knowledge, has never been used to prepare amide-substituted phthalonitriles, the natural precursors for the synthesis of phthalocyanines. Some examples of phthalocyanines prepared thereof are also reported, along with their full spectroscopic characterization and photophysical properties initial assessment. | pt |
dc.language.iso | eng | pt |
dc.publisher | MDPI | pt |
dc.relation | PEst-OE/QUI/UI0313/2014 | pt |
dc.relation | PT2020 POCI-01-0145-FEDER-027996 | pt |
dc.relation | PTDC/QEQ-MED/3521/2014 | pt |
dc.relation | PTDC/QUI-OUT/27996/2017 | pt |
dc.relation | SFRH/BPD/99698/2014 | pt |
dc.relation | PD/BD/128317/2017 | pt |
dc.relation | PD/BD/128318/2017 | pt |
dc.relation | PD/BI/135341/2017 | pt |
dc.rights | openAccess | pt |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt |
dc.subject | peptide bond | pt |
dc.subject | phthalonitriles | pt |
dc.subject | phthalocyanines | pt |
dc.subject | aminocarbonylation | pt |
dc.subject | palladium catalysts | pt |
dc.title | A New Tool in the Quest for Biocompatible Phthalocyanines: Palladium Catalyzed Aminocarbonylation for Amide Substituted Phthalonitriles and Illustrative Phthalocyanines Thereof | pt |
dc.type | article | - |
degois.publication.firstPage | 480 | pt |
degois.publication.issue | 10 | pt |
degois.publication.title | Catalysts | pt |
dc.peerreviewed | yes | pt |
dc.identifier.doi | 10.3390/catal8100480 | pt |
degois.publication.volume | 8 | pt |
dc.date.embargo | 2018-01-01 | * |
uc.date.periodoEmbargo | 0 | pt |
item.fulltext | Com Texto completo | - |
item.grantfulltext | open | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
item.openairetype | article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0003-2094-4781 | - |
crisitem.author.orcid | 0000-0003-4958-7677 | - |
Appears in Collections: | I&D CQC - Artigos em Revistas Internacionais |
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