Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/107451
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Pineiro, Marta | - |
dc.contributor.author | Gomes, Carla | - |
dc.contributor.author | Peixoto, Mariana | - |
dc.date.accessioned | 2023-07-12T11:35:32Z | - |
dc.date.available | 2023-07-12T11:35:32Z | - |
dc.date.issued | 2021 | - |
dc.identifier.issn | 1751-8253 | pt |
dc.identifier.issn | 1751-7192 | pt |
dc.identifier.uri | https://hdl.handle.net/10316/107451 | - |
dc.description.abstract | The synthesis of chlorins was performed by hydrogenation of porphyrins using diimide generated and consumed under mechanical activation. The reaction conditions achievable under ball milling, absence of solvent and use of hydrazine hydrate as diimide source, allowed the hydrogenation of porphyrins with high conversion, high selectivity, and nearly ideal sustainability scores (atom economy of 97% and E-factor of 0.96). | pt |
dc.language.iso | eng | pt |
dc.publisher | Taylor&Francis | pt |
dc.relation | FCT grant number PD/BD/135531/2018 | pt |
dc.rights | openAccess | pt |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt |
dc.subject | Mechanochemistry | pt |
dc.subject | porphyrin | pt |
dc.subject | chlorin | pt |
dc.subject | hydrazine hydrate | pt |
dc.subject | reduction | pt |
dc.title | Mechanochemical in situ generated gas reactant for the solvent-free hydrogenation of porphyrins | pt |
dc.type | article | - |
degois.publication.firstPage | 339 | pt |
degois.publication.lastPage | 344 | pt |
degois.publication.issue | 2 | pt |
degois.publication.title | Green Chemistry Letters and Reviews | pt |
dc.peerreviewed | yes | pt |
dc.identifier.doi | 10.1080/17518253.2021.1921283 | pt |
degois.publication.volume | 14 | pt |
dc.date.embargo | 2021-01-01 | * |
uc.date.periodoEmbargo | 0 | pt |
item.fulltext | Com Texto completo | - |
item.languageiso639-1 | en | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.openairetype | article | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0002-7460-3758 | - |
crisitem.author.orcid | 0000-0003-2540-7029 | - |
Appears in Collections: | I&D CQC - Artigos em Revistas Internacionais |
Files in This Item:
File | Description | Size | Format | |
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Pineiro2021GreenChemLettRev.pdf | 1.39 MB | Adobe PDF | View/Open |
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