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https://hdl.handle.net/10316/10621| Title: | Excited-State Proton Transfer in Gas-Expanded Liquids: The Roles of Pressure and Composition in Supercritical CO2/Methanol Mixtures | Authors: | Nunes, Rui M. D. Arnaut, Luís G. Solntsev, Kyril M. Tolbert, Laren M. Formosinho, Sebastião J. |
Issue Date: | 31-Aug-2005 | Publisher: | American Chemical Society | Citation: | Journal of the American Chemical Society. 127:34 (2005) 11890-11891 | Abstract: | Excited-state proton transfer from 5,8-dicyano-2-naphthol to methanol takes place in CO2/methanol mixtures, in the pressure and temperature ranges of supercritical CO2. The efficiency of the proton-transfer step decreases with the pressure. This is assigned to the perturbation of the methanol clusters solvating the naphthol. | URI: | https://hdl.handle.net/10316/10621 | ISSN: | 0002-7863 | DOI: | 10.1021/ja052416o | Rights: | openAccess |
| Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
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| Excited-State Proton Transfer in Gas-Expanded Liquids.pdf | 56.4 kB | Adobe PDF | View/Open |
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