Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/10386
DC Field | Value | Language |
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dc.contributor.author | Gardas, Ramesh L. | - |
dc.contributor.author | Freire, Mara G. | - |
dc.contributor.author | Carvalho, Pedro J. | - |
dc.contributor.author | Marrucho, Isabel M. | - |
dc.contributor.author | Fonseca, Isabel M. A. | - |
dc.contributor.author | Ferreira, Abel G. M. | - |
dc.contributor.author | Coutinho, João A. P. | - |
dc.date.accessioned | 2009-06-26T13:02:11Z | - |
dc.date.available | 2009-06-26T13:02:11Z | - |
dc.date.issued | 2007-01-11 | - |
dc.identifier.citation | Journal of Chemical & Engineering Data. 52:1 (2007) 80-88 | en_US |
dc.identifier.issn | 0021-9568 | - |
dc.identifier.uri | https://hdl.handle.net/10316/10386 | - |
dc.description.abstract | This work addresses the experimental measurements of the pressure (0.10 < p/MPa < 10.0) and temperature (293.15 < T/K < 393.15) dependence of the density and derived thermodynamic properties, such as the isothermal compressibility, the isobaric expansivity, the thermal pressure coefficient, and the pressure dependence of the heat capacity of several imidazolium-based ionic liquids (ILs), namely, 1-butyl-3-methylimidazolium tetrafluoroborate, [bmim][BF4]; 3-methyl-1-octylimidazolium tetrafluoroborate, [omim][BF4]; 1-hexyl-3-methylimidazolium hexafluorophosphate, [hmim][PF6]; 3-methyl-1-octylimidazolium hexafluorophosphate, [omim][PF6]; 1-butyl-2,3-dimethylimidazolium hexafluorophosphate, [bmmim][PF6]; and 1-butyl-3-methylimidazolium trifluoromethansulfonate, [bmim][CF3SO3]. These ILs were chosen to provide an understanding of the influence of the cation alkyl chain length, the number of cation substitutions, and the anion influence on the properties under study. The influence of water content in the density was also studied for the most hydrophobic IL used, [omim][PF6]. A simple ideal-volume model was employed for the prediction of the imidazolium molar volumes at ambient conditions, which proved to agree well with the experimental results. | en_US |
dc.description.tableofcontents | http://dx.doi.org/10.1021/je060247x | - |
dc.language.iso | eng | en_US |
dc.publisher | American Chemical Society | en_US |
dc.rights | openAccess | eng |
dc.title | High-Pressure Densities and Derived Thermodynamic Properties of Imidazolium-Based Ionic Liquids | en_US |
dc.type | article | en_US |
dc.identifier.doi | 10.1021/je060247x | - |
item.fulltext | Com Texto completo | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | open | - |
item.languageiso639-1 | en | - |
item.openairetype | article | - |
item.cerifentitytype | Publications | - |
crisitem.author.dept | Faculty of Arts and Humanities | - |
crisitem.author.dept | Faculty of Sciences and Technology | - |
crisitem.author.dept | Faculty of Sciences and Technology | - |
crisitem.author.parentdept | University of Coimbra | - |
crisitem.author.parentdept | University of Coimbra | - |
crisitem.author.researchunit | CEAACP - Center for Studies in Archeology, Arts and Heritage | - |
crisitem.author.researchunit | CIEPQPF – Chemical Process Engineering and Forest Products Research Centre | - |
crisitem.author.researchunit | CIEPQPF – Chemical Process Engineering and Forest Products Research Centre | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0003-3749-3542 | - |
crisitem.author.orcid | 0000-0002-0983-1404 | - |
crisitem.author.orcid | 0000-0002-8316-200X | - |
Appears in Collections: | FCTUC Eng.Química - Artigos em Revistas Internacionais |
Files in This Item:
File | Description | Size | Format | |
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High-Pressure Densities and Derived Thermodynamic Properties.pdf | 107.53 kB | Adobe PDF | View/Open |
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