Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/5256
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dc.contributor.authorDiéguez, M.-
dc.contributor.authorRuiz, A.-
dc.contributor.authorClaver, C.-
dc.contributor.authorPereira, M. M.-
dc.contributor.authorFlor, M. T.-
dc.contributor.authorBayón, J. C.-
dc.contributor.authorSerra, M. E. S.-
dc.contributor.authorRocha Gonsalves, A. M. d'A.-
dc.date.accessioned2008-09-01T15:06:37Z-
dc.date.available2008-09-01T15:06:37Z-
dc.date.issued1999en_US
dc.identifier.citationInorganica Chimica Acta. 295:1 (1999) 64-70en_US
dc.identifier.urihttp://hdl.handle.net/10316/5256-
dc.description.abstractComplexes [Rh(cod)(degusR)]ClO4, where cod is 1,5-cyclooctadiene and degusR represents the homochiral dithioethers (R,R)-1-benzyl-3,4-bis(methylsulfanyl)pyrrolidine, (R,R)-1-benzyl-3,4-bis(isopropylsulfanyl)pyrrolidine and (R,R)-1-benzyl-3,4-bis(phenylsulfanyl)pyrrolidine were prepared and characterized. Their reactivity with CO and PPh3 was investigated. The complexes were assayed as catalysts in hydroformylation of styrene, hydrogenation of acrylic acids and hydroboration of styrene. Although these complexes containing dithioethers behave as catalytic precursors in hydroformylation reaction, the results suggest that mononuclear hydride rhodium carbonyl species is responsible for the catalytic activity. The cationic complexes are not active in the hydrogenation of acrylic acids in the conditions tested. These complexes are moderately active in the hydroboration of styrene with catecholborane, but their selectivities are not satisfactory.en_US
dc.description.urihttp://www.sciencedirect.com/science/article/B6TG5-3XWJKPH-8/1/2d47b8846a016e0aca3487986250181den_US
dc.format.mimetypeaplication/PDFen
dc.language.isoengeng
dc.rightsopenAccesseng
dc.subjectRhodium complexesen_US
dc.subjectDithioether ligandsen_US
dc.subjectHydroformylationen_US
dc.subjectHydrogenationen_US
dc.subjectHydroborationen_US
dc.titleSynthesis, reactivity and catalytic properties of rhodium complexes of (R,R)-1-benzyl-3,4-dithioetherpyrrolidinesen_US
dc.typearticleen_US
dc.identifier.doi10.1016/S0020-1693(99)00309-6-
item.fulltextCom Texto completo-
item.grantfulltextopen-
item.languageiso639-1en-
crisitem.author.deptFaculty of Sciences and Technology-
crisitem.author.deptFaculty of Sciences and Technology-
crisitem.author.parentdeptUniversity of Coimbra-
crisitem.author.parentdeptUniversity of Coimbra-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.orcid0000-0002-4562-7072-
crisitem.author.orcid0000-0001-9987-7301-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
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