Please use this identifier to cite or link to this item: https://hdl.handle.net/10316/5130
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dc.contributor.authorSerra, A. C.-
dc.contributor.authorMarçalo, E. C.-
dc.contributor.authorRocha Gonsalves, A. M. d'A.-
dc.date.accessioned2008-09-01T15:04:28Z-
dc.date.available2008-09-01T15:04:28Z-
dc.date.issued2004en_US
dc.identifier.citationJournal of Molecular Catalysis A: Chemical. 215:1-2 (2004) 17-21en_US
dc.identifier.urihttps://hdl.handle.net/10316/5130-
dc.description.abstractThe stability of biomimetic catalysts is an essential characteristic for them to be of some practical use. The study of the reaction of metalloporphyrin catalysts in hydrogen peroxide oxidations in the presence of benzoic acid allowed to understand whether an intramolecular or intermolecular mechanism is operative in catalyst degradation. Under certain reaction conditions, the presence of a radical inhibitor minimises the catalyst degradation, and therefore, improves the catalytic process.en_US
dc.description.urihttp://www.sciencedirect.com/science/article/B6TGM-4BWYS2W-5/1/8aefbaac0fec5863fe3a0cf7f1dbc44een_US
dc.format.mimetypeaplication/PDFen
dc.language.isoengeng
dc.rightsopenAccesseng
dc.subjectMetalloporphyrinen_US
dc.subjectCatalysten_US
dc.subjectDegradationen_US
dc.subjectHydrogen peroxideen_US
dc.titleA view on the mechanism of metalloporphyrin degradation in hydrogen peroxide epoxidation reactionsen_US
dc.typearticleen_US
dc.identifier.doi10.1016/j.molcata.2004.01.023-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypearticle-
item.cerifentitytypePublications-
item.grantfulltextopen-
item.fulltextCom Texto completo-
item.languageiso639-1en-
crisitem.author.researchunitCEMMPRE - Centre for Mechanical Engineering, Materials and Processes-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.orcid0000-0001-8664-2757-
crisitem.author.orcid0000-0001-9987-7301-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
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