Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/5130
Title: A view on the mechanism of metalloporphyrin degradation in hydrogen peroxide epoxidation reactions
Authors: Serra, A. C. 
Marçalo, E. C. 
Rocha Gonsalves, A. M. d'A. 
Keywords: Metalloporphyrin; Catalyst; Degradation; Hydrogen peroxide
Issue Date: 2004
Citation: Journal of Molecular Catalysis A: Chemical. 215:1-2 (2004) 17-21
Abstract: The stability of biomimetic catalysts is an essential characteristic for them to be of some practical use. The study of the reaction of metalloporphyrin catalysts in hydrogen peroxide oxidations in the presence of benzoic acid allowed to understand whether an intramolecular or intermolecular mechanism is operative in catalyst degradation. Under certain reaction conditions, the presence of a radical inhibitor minimises the catalyst degradation, and therefore, improves the catalytic process.
URI: http://hdl.handle.net/10316/5130
DOI: 10.1016/j.molcata.2004.01.023
Rights: openAccess
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais

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