Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/33048
DC Field | Value | Language |
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dc.contributor.author | Pedrosa, Jorge | - |
dc.contributor.author | Gamelas, J. A. F. | - |
dc.contributor.author | Lourenço, Ana F. | - |
dc.contributor.author | Ferreira, Paulo J. | - |
dc.date.accessioned | 2016-11-23T23:20:40Z | - |
dc.date.available | 2016-11-23T23:20:40Z | - |
dc.date.issued | 2016-02-24 | - |
dc.identifier.issn | 0927-7757 | por |
dc.identifier.uri | https://hdl.handle.net/10316/33048 | - |
dc.description.abstract | The physico chemical surface properties of precipitated calcium carbonate (PCC) modified with silica by sol-gel method were evaluated using inverse gas chromatography and compared to those of the original PCC. The modification of the surface of PCC crystals by a dense film of silica provided a slight decrease of the dispersive component of the surface energy and a significant decrease of the specific component of the work of adhesion with trichloromethane (a Lewis acidic probe). In addition, interactions measured with weak Lewis bases (1-alkenes) also revealed differences between PCC and PCC-silica samples. Differences in the surface properties (namely of the Lewis acid-base ones) of PCCs modified with distinct silica content (ca. 22 and 30 wt%), were also found, and were interpreted as being due to the different accessibility of silanol groups (Si-OH) on the materials surface: a higher prevalence of these acidic groups in the material with lower silica content increases the specific affinity to Lewis basic probes and decreases the affinity to Lewis acidic probe. X-ray photoelectron spectroscopy results confirmed the presence of silica on PCC, with a higher Si/Ca atomic ratio being found for the material with higher silica content. | por |
dc.language.iso | eng | por |
dc.publisher | Elsevier | por |
dc.rights | openAccess | por |
dc.subject | Precipitated calcium carbonate | por |
dc.subject | Silica | por |
dc.subject | Sol-gel method | por |
dc.subject | Surface physical-chemical properties | por |
dc.subject | IGC | por |
dc.subject | XPS | por |
dc.title | Surface properties of calcium carbonate modified with silica by sol-gel method | por |
dc.type | article | - |
degois.publication.firstPage | 1 | por |
degois.publication.lastPage | 7 | por |
degois.publication.title | Colloids and Surfaces A: Physicochemical and Engineering Aspects | por |
dc.relation.publisherversion | http://www.sciencedirect.com/science/article/pii/S0927775716300863 | por |
dc.peerreviewed | yes | por |
dc.identifier.doi | 10.1016/j.colsurfa.2016.02.020 | por |
dc.identifier.doi | 10.1016/j.colsurfa.2016.02.020 | - |
degois.publication.volume | 497 | por |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.openairetype | article | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.fulltext | Com Texto completo | - |
item.languageiso639-1 | en | - |
crisitem.author.researchunit | CIEPQPF – Chemical Process Engineering and Forest Products Research Centre | - |
crisitem.author.researchunit | CIEPQPF – Chemical Process Engineering and Forest Products Research Centre | - |
crisitem.author.researchunit | CIEPQPF – Chemical Process Engineering and Forest Products Research Centre | - |
crisitem.author.researchunit | CIEPQPF – Chemical Process Engineering and Forest Products Research Centre | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0002-6900-1592 | - |
crisitem.author.orcid | 0000-0002-1474-767X | - |
crisitem.author.orcid | 0000-0002-2860-9833 | - |
crisitem.author.orcid | 0000-0002-4503-6811 | - |
Appears in Collections: | FCTUC Eng.Química - Artigos em Revistas Internacionais |
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File | Description | Size | Format | |
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Surface properties of calcium carbonate modified with silica by sol-gel methods.pdf | 246.9 kB | Adobe PDF | View/Open |
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