Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/10620
Title: Rotational Isomerism in Acetic Acid: The First Experimental Observation of the High-Energy Conformer
Authors: Maçôas, Ermelinda M. S. 
Khriachtchev, Leonid 
Pettersson, Mika 
Fausto, Rui 
Räsänen, Markku 
Issue Date: 31-Dec-2003
Publisher: American Chemical Society
Citation: Journal of the American Chemical Society. 125:52 (2003) 16188-16189
Abstract: The high-energy conformer of acetic acid (cis-AA) is produced in an Ar matrix by vibrational excitation of the OH stretching overtone of the ground conformational state (trans-AA). IR-absorption spectroscopy provides a clear identification of the reaction product. cis-AA converts back to trans-AA in a time scale of minutes at 8 K by tunneling.
URI: http://hdl.handle.net/10316/10620
ISSN: 0002-7863
DOI: 10.1021/ja038341a
Rights: openAccess
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais

Files in This Item:
Show full item record

SCOPUSTM   
Citations

107
checked on Nov 11, 2022

WEB OF SCIENCETM
Citations 1

100
checked on Aug 2, 2022

Page view(s)

268
checked on Dec 5, 2022

Download(s) 50

388
checked on Dec 5, 2022

Google ScholarTM

Check

Altmetric

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.